Rice University researchers have developed a smart material that adjusts its transparency with changes in temperature, outperforming similar materials in terms of durability, transparency and responsiveness. The new polymer blend could significantly enhance energy efficiency for indoor space cooling, according to a new study published in Joule.
Cooling off can be a matter of life or death, but air conditioning ⎯ when and if available ⎯ already accounts for 7% of the world’s energy use and 3% of carbon emissions. With temperatures hitting record highs and heat waves growing more frequent worldwide, the need for more efficient ways to keep indoor temperatures in check has also grown more urgent.
One way to mitigate the issue involves coating windows with materials that keep heat out while still allowing light to pass through. One such class of materials is thermochromics, yet existing varieties are still too expensive and short-lived to make a feasible choice for use in buildings, vehicles and wherever else needed.
The new salted polymer blend system developed by Rice engineers in the Nanomaterials Laboratory led by Pulickel Ajayan overcomes these challenges, potentially enabling the large-scale deployment of thermochromics as an energy-efficient indoor space cooling technology.
“Imagine a window that becomes less transparent as the day gets warmer, keeping interiors cool without consuming energy,” said Sreehari Saju, a materials science and nanoengineering doctoral student at Rice who is a co-lead author on the study. “Our formulation leverages both organic and inorganic components to overcome the limitations of existing thermochromic materials such as short lifespans and high costs.
“Moreover, this material’s thermic response is well-matched to real-world environmental demands. We think that smart windows made from this material could significantly reduce energy consumption in buildings, making a tangible impact on both energy costs and carbon footprint.”
The researchers combined experimental methods with computational simulations to understand the material’s behavior under different environmental and architectural settings. For instance, they assessed how the material would perform in specific urban areas around the world to get a sense of its potential impact when deployed at scale.
“Our approach was unique because it required a precise balance of materials and techniques that had not been previously explored in this combination, offering a new pathway for developing smart materials,” said Anand Puthirath, a research scientist in the Ajayan research group and co-lead author on the study. “We conducted comprehensive experiments to characterize the properties of the material, as well environmental stability and durability testing, showing that our blend can outperform existing thermochromics.”
The researchers synthesized the material by mixing two polymers with a type of salt and worked on optimizing the composition to achieve smooth transitions between transparent and opaque states with temperature fluctuations. Their findings show that the new thermochromic blend is not only highly effective in regulating solar radiation but also remarkably durable with an estimated lifespan of 60 years.
“These research findings set new benchmarks in thermochromics’ durability and performance and particularly in a simple practically viable system,” said Ajayan, the corresponding author on the study and Rice’s Benjamin M. and Mary Greenwood Anderson Professor of Engineering and professor and department chair of materials science and nanoengineering. “Our work addresses a critical challenge in sustainable architecture, offering a practical and scalable solution for enhancing energy efficiency in buildings.”
The thermochromic behavior of the material was studied in collaboration with Professor Yi Long and her doctoral student, Shancheng Wang, from the Department of Electronic Engineering at the Chinese University of Hong Kong, Sha Tin.
The research was supported by the Science and Engineering Research Board, India; the Air Force Office of Scientific Research (FA9550-20RXCOR057); the Robert A. Welch Foundation (C-1509); the Global STEM Professorship Scheme sponsored by the Government of the Hong Kong Special Administrative Region; and the Chinese University of Hong Kong Startup Fund. The content in this press release is solely the responsibility of the authors and does not necessarily represent the official views of the supporting entities.
- Peer-reviewed paper:
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“Thermochromic polymer blends” | Joule | DOI: 10.1016/j.joule.2024.07.020
Authors: Sreehari Saju, Anand Puthirath, Shancheng Wang, Thierry Tsafack, Lucas K. Beagle, Andrey Baydin, Nithya Chakingal, Natsumi Komatsu, Fuyang Tay, Arvin Sharma, Rohini Sreenivasan, Junichiro Kono, Robert Vajtai, Nicholas Glavin, Yi Long and Pulickel Ajayan
https://www.sciencedirect.com/science/article/pii/S2542435124003490?via%3Dihub - Video is available at:
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https://youtu.be/c0XtnZnjS60 (Video by Brandon Martin/Rice University)
- Media downloads:
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https://drive.google.com/drive/folders/1_BlKV8itN_C42jZ6i7_EnU7-Ua9zAVCJ?usp=sharing
CAPTION: Rice University research scientist Anand Puthirath (left) and Ph.D. candidate Sreehari Saju with a piece of glass treated with a newly developed salted polymer blend system with outstanding thermochromic properties. (Photo by Jeff Fitlow/Rice University)
CAPTION: Photo viewed through a piece of glass treated with a thermochromic blend (left photo) that is the subject of a new study published in Joule. Rice University engineers Anand Puthirath and Sreehari Saju hold glass samples treated with the thermochromic blend (right photo). (Photos by Jeff Fitlow/Rice University)
CAPTION: Rice University doctoral student Sreehari Saju (left photo) holds a glass sample treated with the high-performing thermochromic blend. The new thermochromic material developed in the lab of Pulickel Ajayan is added onto a glass plate (right photo). (Photos by Jeff Fitlow/Rice University)
CAPTION: Rice’s Anand Puthirath and Sreehari Saju (left photo) are lead co-authors on a study published in Joule. Puthirath holds a glass sample treated with the study’s high-performing thermochromic blend (right photo). (Photos by Jeff Fitlow/Rice University)
CAPTION: Graphic representation (left) of the thermochromic effect observed in transparent flexible polymer blends ⎯ transparency reduces when the temperature outside is above room temperature. Visual demonstration (top right panel) of transparency variation with temperature. Graph representation (bottom right panel) of indoor temperature with pristine glass (red) versus glass coated with thermochromic polymer film (green). (Image courtesy of Pulickel Ajayan’s Nanomaterials Laboratory at Rice University.)