2-D material a brittle surprise

Rice researchers finds molybdenum diselenide not as strong as they thought 

Scientists at Rice University have discovered that an atom-thick material being eyed for flexible electronics and next-generation optical devices is more brittle than they expected.

The Rice team led by materials scientist Jun Lou tested the tensile strength of two-dimensional, semiconducting molybdenum diselenide and discovered that flaws as small as one missing atom can initiate catastrophic cracking under strain.

The team’s report appears this month in Advanced Materials.

The finding may cause industry to look more carefully at the properties of 2-D materials before incorporating them in new technologies, he said.

“It turns out not all 2-D crystals are equal,” said Lou, a Rice professor of materials science and nanoengineering. “Graphene is a lot more robust compared with some of the others we’re dealing with right now, like this molybdenum diselenide. We think it has something to do with defects inherent to these materials.”

The defects could be as small as a single atom that leaves a vacancy in the crystalline structure, he said. “It’s very hard to detect them,” he said. “Even if a cluster of vacancies makes a bigger hole, it’s difficult to find using any technique. It might be possible to see them with a transmission electron microscope, but that would be so labor-intensive that it wouldn’t be useful.”

A nanomechanical device designed by Rice scientists is used to measure the strength of two-dimensional nanomaterials like molybdenum diselenide, the subject of a recent Rice study that found it far more brittle than graphene. Courtesy of the Lou Group

Molybdenum diselenide is a dichalcogenide, a two-dimensional semiconducting material that appears as a graphene-like hexagonal array from above but is actually a sandwich of metallic atoms between two layers of chalcogen atoms, in this case, selenium. Molybdenum diselenide is being considered for use as transistors and in next-generation solar cells, photodetectors and catalysts as well as electronic and optical devices.

Lou and colleagues measured the material’s elastic modulus, the amount of stretching a material can handle and still return to its initial state, at 177.2 (plus or minus 9.3) gigapascals. Graphene is more than five times as elastic. They attributed the large variation to pre-existing flaws of between 3.6 and 77.5 nanometers.

Its fracture strength, the amount of stretching a material can handle before breaking, was measured at 4.8 (plus or minus 2.9) gigapascals. Graphene is nearly 25 times stronger.

Part of the project led by Rice postdoctoral researcher Yingchao Yang required moving molybdenum diselenide from a growth chamber in a chemical vapor deposition furnace to a microscope without introducing more defects. Yang solved the problem using a dry transfer process in place of a standard acid washing that would have ruined the samples.

To test samples, Yang placed rectangles of molybdenum diselenide onto a sensitive electron microscope platform invented by the Lou group. Natural van der Waals forces held the samples in place on springy cantilever arms that measured the applied stress.

When seen from above, the atoms in two-dimensional molybdenum diselenide resemble a hexagonal grid, like graphene. But in reality, the darker molybdenum atoms are sandwiched between top and bottom layers of selenide atoms. Rice University researchers tested the material for its tensile strength. Courtesy of the Lou Group

Lou said the group attempted to measure the material’s fracture toughness, an indicator of how likely cracks are to propagate, as they had in an earlier study on graphene. But they found that pre-cutting cracks into molybdenum diselenide resulted in it shattering before stress could be applied, he said.

“The important message of this work is the brittle nature of these materials,” Lou said. “A lot of people are thinking about using 2-D crystals because they’re inherently thin. They’re thinking about flexible electronics because they are semiconductors and their theoretical elastic strain should be very high. According to our calculations, they can be stretched up to 10 percent.

“But in reality, because of the inherent defects, you rarely can achieve that much strain. The samples we have tested so far broke at 2 to 3 percent (of the theoretical maximum) at most,” Lou said. “That should still be fine for most flexible applications, but unless they find a way to quench the defects, it will be very hard to achieve the theoretical limits.”

Co-authors of the paper are Rice graduate students Emily Hacopian, Weibing Chen, Jing Zhang and Bo Li, alumna Yongji Gong and Pulickel Ajayan, chair of Rice’s Department of Materials Science and NanoEngineering, the Benjamin M. and Mary Greenwood Anderson Professor in Engineering and a professor of chemistry; Xing Li of Rice and Peking University, China; Minru Wen of Tsinghua University, China, and the Georgia Institute of Technology; Wu Zhou of Oak Ridge National Laboratory, Oak Ridge, Tenn.; Qing Chen of Peking University; and Ting Zhu of the Georgia Institute of Technology.

The research was supported by the Air Force Office of Scientific Research, the Welch Foundation, the Department of Energy Office of Basic Energy Sciences, the National Science Foundation and the National Science Foundation of China.